Deacetylative Aryl Migration of Diaryliodonium Salts with C(sp2)-N Bond Formation toward ortho-Iodo N-Aryl Sulfonamides.
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DOI: 10.1021/acs.orglett.0c01024
Abstract: An unprecedented approach of metal-free C(sp2)-N bond formation via deacetylation/intramolecular aryl migration is demonstrated with novel N-sulfonamide substituted diaryliodonium salts. The reaction provides a variety of ortho-iodo N-aryl sulfonamides. The products were employed in several… read more here.
Keywords: ortho iodo; diaryliodonium salts; bond formation; aryl migration ... See more keywords