Articles with "ortho meta" as a keyword



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Synthesis and toxicity profile in 293 human embryonic kidney cells of the β D-glucuronide derivatives of ortho-, meta- and para-cresol.

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Published in 2020 at "Carbohydrate research"

DOI: 10.1016/j.carres.2020.108225

Abstract: The formation of β-glucuronides is a major route by which mammals detoxify and remove breakdown products, such as l-tyrosine, as well as many xenobiotics, from their systems. In humans, dietary l-tyrosine is broken down largely… read more here.

Keywords: cresol; cresyl glucuronides; ortho meta; cresyl ... See more keywords
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Amine vs. carboxylic acid protonation in ortho-, meta-, and para-aminobenzoic acid: An IRMPD spectroscopy study.

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Published in 2017 at "Journal of molecular spectroscopy"

DOI: 10.1016/j.jms.2016.10.020

Abstract: Infrared multiple photon dissociation (IRMPD) spectroscopy and computational chemistry are applied to the ortho-, meta-, and para- positional isomers of aminobenzoic acid to investigate whether the amine or the carboxylic acid are the favored sites… read more here.

Keywords: ortho meta; aminobenzoic acid; carboxylic acid; spectroscopy ... See more keywords
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How do isomeric ortho, meta and paradicationic ionic liquids impact the production of 5-hydroxymethylfurfural?

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Published in 2017 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2017.02.076

Abstract: Abstract This research investigates the influence of the subsituent's relative positions (ortho, meta, or para) of dicationic ionic liquids (ILs) on the catalytic production of 5-hydroxymethylfurfural (HMF). This research started with the facile synthesis of… read more here.

Keywords: ortho meta; meta; production hydroxymethylfurfural; isomeric ortho ... See more keywords
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Hinged Bipodal Furoylthiourea-Based Ru(II)-Arene Complexes: Effect of (ortho, meta, or para)-Substitution on Coordination and Anticancer Activity.

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Published in 2023 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.3c00073

Abstract: We set out to design and synthesize bipodal ligands with the phenyl group as the spacer and varied the substitution on the spacer between ortho (L1), meta (L2), and para (L3). The respective ligands and… read more here.

Keywords: ortho meta; anticancer activity; substitution; meta para ... See more keywords
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Ruthenium-Catalyzed ortho- and meta-H/D Exchange of Arenes.

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Published in 2019 at "Organic letters"

DOI: 10.1021/acs.orglett.9b03955

Abstract: Ruthenium-catalyzed aromatic H/D exchange in [D4]acetic acid has been developed. By using N-heteroarenes as directing groups, both ortho and meta positions are selectively deuterated with high levels of D incorporation. Moreover, this strategy provides an… read more here.

Keywords: catalyzed ortho; exchange arenes; meta exchange; ortho meta ... See more keywords
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Splitting the Ring: Impact of Ortho and Meta Pi Conjugation Pathways through Disjointed [8]Cycloparaphenylene Electronic Materials.

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Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c00419

Abstract: In this report, we describe the synthesis and electronic properties of small-molecule and polymeric [8]cycloparaphenylenes ([8]CPPs) with disjointed pi-conjugated substituents. Arylene-ethynylene linkers were installed on opposite sides of the [8]CPP nanohoop as separated by three… read more here.

Keywords: ring impact; splitting ring; ortho meta; conjugation pathways ... See more keywords
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The implications of Ortho-, Meta- and Para- Directors on the In-Vitro Photodynamic Antimicrobial Chemotherapy Activity of Cationic Pyridyl-dihydrothiazole Phthalocyanines.

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Published in 2022 at "Photodiagnosis and photodynamic therapy"

DOI: 10.2139/ssrn.4118238

Abstract: Cationic Zn phthalocyanine complexes derived by alkylation reaction of tetra-(pyridinyloxy) phthalocyanines at the ortho, meta, and para positions to form Zn (II) Tetrakis 3-(4-(2-pyridin-1-ium-1-yl) butyl)-2-mercapto-4,5-dihydrothiazol-3-ium phthalocyanine (2), Zn (II) Tetrakis 3-(4-(3-pyridin-1-ium-1-yl) butyl)-2-mercapto-4,5-dihydrothiazol-3-ium phthalocyanine (4) and… read more here.

Keywords: ium; meta para; antimicrobial chemotherapy; phthalocyanine ... See more keywords