The synthesis and characterization of an ortho-metallated iridium(III) hydride based on a pyridylpyrrole ligand
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DOI: 10.1016/j.poly.2020.114515
Abstract: Abstract Treatment of [Ir(PPh3)3Cl] with the 2-(1H-pyrrol-2-yl)pyridine (Hpp) ligand under refluxing toluene affords the iridium(III) hydride complex [Ir(H)Cl(pp)(PPh3)2] (1), whereas in the simultaneous presence of KOtBu the reaction gives iridium(III) hydride isomers, namely ortho-metallated triphenylphosphine… read more here.
Keywords: iii hydride; ligand; iridium iii; ortho metallated ... See more keywords