Rigidification of Poly(p-phenylene)s through ortho-Phenyl Substitution
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecules"
DOI: 10.1021/acs.macromol.0c00810
Abstract: A sterically π-congested ortho-phenylated poly(p-phenylene) (PPP) has been synthesized with unprecedentedly high molecular weights up to 29 kDa after fractionation, as confirmed by gel permeation chromatography coupled with a multiangle laser light scattering detector. The… read more here.
Keywords: ortho phenyl; phenyl substitution; rigidification poly; phenylene ortho ... See more keywords
Recent advances in bridged structures as 3D bioisosteres of ortho-phenyl rings in medicinal chemistry applications.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc00816f
Abstract: In recent years, a lot of scientists have tried to replace the phenyl ring in bioactive compounds with saturated 3D bioisosteres to obtain novel patentable structures in medicinal chemistry. Among these structures, bridged polycyclic compounds,… read more here.
Keywords: chemistry; ortho phenyl; chemistry applications; recent advances ... See more keywords