Selective Ortho Thiolation Enabled by Tuning the Ancillary Ligand in Palladium/Norbornene Catalysis.
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DOI: 10.1021/acs.orglett.9b00923
Abstract: Site-selective introduction of a sulfur group into aromatic compounds is essential and useful in organic, material, and pharmaceutical chemistry. A palladium/norbornene-catalyzed chemoselective ortho thiolation of aryl halides was reported. The selectivity of reductive elimination for… read more here.
Keywords: ancillary ligand; tuning ancillary; ortho thiolation; palladium norbornene ... See more keywords