Closing the "One Monomer-Two Polymers-One Monomer" Loop via Orthogonal (De)polymerization of a Lactone/Olefin Hybrid.
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DOI: 10.1021/jacs.1c12278
Abstract: Two well-known low-ceiling-temperature (LCT) monomers, γ-butyrolactone (γ-BL) toward ring-opening polymerization (ROP) to polyester and cyclohexene toward ring-opening metathesis polymerization (ROMP) to poly(cyclic olefin), are notoriously "nonpolymerizable". Here we present a strategy to render not only… read more here.
Keywords: rop; monomer; lactone; orthogonal polymerization ... See more keywords