Articles with "os3 ncme" as a keyword



Photo by ryancp from unsplash

Facile Os-Os bond cleavage in the reactions of [Os3(CO)10(NCMe)2] and [Os3(CO)10(μ-H)2] with tetramethylthiuram disulfide (tmtd): Syntheses and crystal structures of new polynuclear osmium carbonyl complexes containing a dimethyldithiocarbamate ligand(s)

Sign Up to like & get
recommendations!
Published in 2020 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2020.121133

Abstract: Abstract The reaction of the labile triosmium cluster [Os3(CO)10(NCMe)2] with tetramethylthiuram disulfide [(Me2NCS2)2, tmtd] has been investigated at room temperature. Conducting the reaction under mild conditions has permitted the isolation of the three new polynuclear… read more here.

Keywords: osmium; tetramethylthiuram disulfide; os3 ncme; new polynuclear ... See more keywords