Synthesis and derivatisation of ceric tris(tert-butoxy)siloxides.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc06499c
Abstract: Metathesis reactions involving cerium(iv) complexes are generally hampered by a high tendency for reduction to the favoured trivalent state and a preference for ligand redistribution. Heteroleptic ceric Ce[OSi(OtBu)3]3Cl(thf) is easily obtained from the oxidation of… read more here.
Keywords: derivatisation ceric; osi otbu; synthesis derivatisation; tert butoxy ... See more keywords
Hetero-bimetallic alkali titanosilicates [MOTi{OSi(OtBu)3}3]2 (M = Li-Cs) with terminal Ti-O- groups.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00939k
Abstract: The molecular titanosilicate [(tBuO3)3SiO]3TiNEt2 (1) was obtained from the reaction between silanol (tBuO3)3SiOH and titanium amide Ti(NEt2)4. The reaction of 1 with alkali metal hydroxides MOH (M = Li, Na, K, Rb, Cs) offers a… read more here.
Keywords: hetero bimetallic; moti osi; bimetallic alkali; titanosilicates moti ... See more keywords