Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”
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DOI: 10.1021/acs.organomet.7b00707
Abstract: Osmium nitride chemistry is dominated by osmium(VI) in octahedral or square-pyramidal coordination. The stability of the d2 configuration and preference of the strong σ- and π-donor nitride for apical coordination is in line with the… read more here.
Keywords: osmium; coordination; osmium nitrides; four five ... See more keywords