Using molten salts to probe outer-coordination sphere effects on lanthanide(III)/(II) electron-transfer reactions.
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DOI: 10.1039/d1dt02708e
Abstract: Controlling structure and reactivity by manipulating the outer-coordination sphere around a given reagent represents a longstanding challenge in chemistry. Despite advances toward solving this problem, it remains difficult to experimentally interrogate and characterize outer-coordination sphere… read more here.
Keywords: coordination sphere; outer coordination; electron; sphere effects ... See more keywords