Mechanistic Studies on the Epoxidation of Alkenes by Macrocyclic Manganese Porphyrin Catalysts
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DOI: 10.1002/ejoc.202200280
Abstract: Abstract Macrocyclic metal porphyrin complexes can act as shape‐selective catalysts mimicking the action of enzymes. To achieve enzyme‐like reactivity, a mechanistic understanding of the reaction at the molecular level is needed. We report a mechanistic… read more here.
Keywords: epoxidation alkenes; cage; mechanistic studies; oxo ligand ... See more keywords