Synthesis of (μ2,η3-allyl-η5-oxapentadienyl)diiron pentacarbonyl complexes, an unusual reaction product from η4-(vinylketene)Fe(CO)3 complexes: structure and electron density distribution analysis.
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DOI: 10.1039/d2dt03700a
Abstract: The synthesis of a series of ferrocenylvinylketenes as stable η4-[Fe(CO)3] complexes (3a-f) was successfully accomplished through the reaction of η2-[Fe(CO)4] complexes under mild carbonylation conditions. The reactivity of 3a-f under thermal conditions afforded the unexpected… read more here.
Keywords: oxapentadienyl diiron; density distribution; diiron pentacarbonyl; allyl oxapentadienyl ... See more keywords