Iodine-Catalyzed Functionalization of Primary Aliphatic Amines to Oxazoles, 1,4-Oxazines, and Oxazinones
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DOI: 10.1021/acsomega.9b03501
Abstract: Unprecedented I2-catalyzed α,α-C(sp3)-H, decarboxylative α-C(sp3)-H, lactonized α-C(sp3)-H, and α,β-C(sp3)-H functionalized 5- and 6-annulation as well as α-C(sp3)-H activated 6-lactonization of primary aliphatic amines are devised under aerobic conditions. The metal-free sustainable strategy was employed for… read more here.
Keywords: iodine catalyzed; primary aliphatic; oxazoles oxazines; catalyzed functionalization ... See more keywords