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Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.04.027
Abstract: Abstract The synthesis of novel of 4,5,6,7-tetrahydrobenzoxazol-2-ones is herein reported. They were obtained in moderate to good yields by a highly regio- and stereoselective Diels-Alder cycloaddition of N-substituted exo-oxazolidin-2-one dienes with chalcones or bis-chalcones as…
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Keywords:
oxazolidin one;
one dienes;
alder cycloaddition;
exo oxazolidin ... See more keywords
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Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.8b02403
Abstract: The synthesis of isocyanurate-free, linear poly(oxazolidin-2-one)s starting from diepoxides and aromatic as well as aliphatic diisocyanates is reported. N-Heterocyclic carbenes (NHCs), liberated in situ from thermally labile CO2 adducts, in combination with Lewis acids of…
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Keywords:
heterocyclic carbenes;
oxazolidin one;
synthesis;
lewis acids ... See more keywords
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Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b03118
Abstract: A highly enantioselective FeII-catalyzed thia-Michael addition to α,β-unsaturated carbonyl derivatives was developed. The scope of the reaction was demonstrated with a selection of aromatic, heterocyclic and aliphatic thiols, and various Michael acceptors. The corresponding β-thioethers…
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Keywords:
feii catalyzed;
thia michael;
catalyzed thia;
michael addition ... See more keywords
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Published in 2018 at "Synthetic Communications"
DOI: 10.1080/00397911.2018.1490771
Abstract: Abstract A stereoselective and simple method for the synthesis of trans-2-hydroxymethyl-N-alkyl-1,3-oxazolidin-2-ones is described. The synthesis involved the reduction of trans-aziridine-2-carboxylates with LiAlH4, followed by a ring opening and a cyclization reaction in the presence of…
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Keywords:
one derivatives;
stereoselective synthesis;
oxazolidin one;
hydroxymethyl oxazolidin ... See more keywords