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Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c01564
Abstract: Cesium carbonate-mediated stereoselective anomeric O-alkylation of a 2N,3O-oxazolidinone-protected d-mannosamine with sugar-derived primary or secondary alkyl triflates afforded the corresponding 2-amino-2-deoxy-β-d-mannosides in moderate to good yields and excellent stereoselectivity. The oxazolidinone ring can be opened with…
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Keywords:
anomeric alkylation;
oxazolidinone;
oxazolidinone protected;
synthesis ... See more keywords