Aerobic Partial Oxidation of Alkanes Using Photodriven Iron Catalysis.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03086
Abstract: Photodriven oxidations of alkanes in trifluoroacetic acid using commercial and synthesized Fe(III) sources as catalyst precursors and dioxygen (O2) as the terminal oxidant are reported. The reactions produce alkyl esters and occur at ambient temperature… read more here.
Keywords: oxidation; partial oxidation; alkanes using; oxidation alkanes ... See more keywords
Copper(ii) complexes with 2,2':6',2''-terpyridine, 2,6-di(thiazol-2-yl)pyridine and 2,6-di(pyrazin-2-yl)pyridine substituted with quinolines. Synthesis, structure, antiproliferative activity, and catalytic activity in the oxidation of alkanes and alcohols with peroxides.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01922g
Abstract: A series of 2,2':6',2''-terpyridine (terpy), 2,6-di(thiazol-2-yl)pyridine (dtpy) and 2,6-di(pyrazin-2-yl)pyridine (dppy) derivatives with n-quinolyl substituents (n = 2 and 4) was used to synthesize five-coordinate complexes [CuCl2(n-quinolyl-terpy)] (1-2), [CuCl2(n-quinolyl-dtpy)] (3-4) and [CuCl2(n-quinolyl-dppy)] (5-6), respectively. The main… read more here.
Keywords: thiazol pyridine; alkanes alcohols; pyrazin pyridine; activity ... See more keywords
Why simple vanadate is inefficient as a catalyst in oxidation of alkanes with H2O2 – the long-standing puzzle is resolved
Sign Up to like & getrecommendations! Published in 2023 at "Dalton Transactions"
DOI: 10.1039/d3dt00967j
Abstract: In contrast to V(V) complexes with various organic ligands, a simple vanadate without any additive is inactive in neutral medium toward the oxidation of alkanes with H2O2. In this work, we discovered that the insufficient… read more here.
Keywords: simple vanadate; vanadate inefficient; alkanes h2o2; inefficient catalyst ... See more keywords