Visible light driven selective oxidation of amines to imines with BiOCl: Does oxygen vacancy concentration matter?
Sign Up to like & getrecommendations! Published in 2018 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2018.01.018
Abstract: Abstract The relationship between oxygen vacancy (OV) concentration of semiconductors and their photocatalytic performances is far from clarified. In this study, by tuning the OV concentration of BiOCl (001) surface via a novel H2O2 treatment… read more here.
Keywords: oxygen; oxygen vacancy; vacancy concentration; oxidation amines ... See more keywords
Visible Light Gold Nanocluster Photocatalyst: Selective Aerobic Oxidation of Amines to Imines
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.6b03509
Abstract: This work demonstrates the synthesis of an efficient photocatalyst, Au25(PPh3)10Cl2(SC3H6SiO3)5/TiO2, for selective oxidation of amines to imines. The photocatalyst is prepared via hydrolysis of Au25(PPh3)10Cl2[(SC3H6Si(OC2H5)3]5 nanoclusters in the presence of TiO2 support. The gold nanoclusters… read more here.
Keywords: oxidation; visible light; photocatalyst; oxidation amines ... See more keywords
Highly Selective Electrocatalytic Oxidation of Amines to Nitriles Assisted by Water Oxidation on Metal-Doped α-Ni(OH)2.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c05403
Abstract: Selective oxidation to synthesize nitriles is critical for feedstock manufacturing in the chemical industry. Current strategies typically involve substitutions of alkyl halides with toxic cyanides or the use of strong oxidation reagents (oxygen or peroxide)… read more here.
Keywords: amines nitriles; metal doped; oxidation; water oxidation ... See more keywords