A Visible‐Light Promoted Amine Oxidation Catalyzed by a Cp*Ir Complex
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DOI: 10.1002/cctc.202000488
Abstract: Through a rapid screening of Cp*Ir complexes based on a turn‐on type fluorescence readout, a [Cp*Ir(dipyrido[3,2‐a : 2’,3’‐c]phenazine)Cl]+ complex was found to catalyze the blue‐light promoted dehydrogenation of N‐heterocycles under physiological conditions. In the dehydrogenation of tetrahydroisoquinolines,… read more here.
Keywords: promoted amine; visible light; oxidation catalyzed; light ... See more keywords
Quantum Chemical Study of the Mechanism of Water Oxidation Catalyzed by a Heterotrinuclear Ru2 Mn Complex.
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DOI: 10.1002/cssc.201802395
Abstract: The heterotrinuclear complex A {[RuII (H2 O)(tpy)]2 (μ-[MnII (H2 O)2 (bpp)2 ])}4+ [tpy=2,2':6',2''-terpyridine, bpp=3,5-bis(2-pyridyl)pyrazolate] was found to catalyze water oxidation both electrochemically and photochemically with [Ru(bpy)3 ]3+ (bpy=2,2'-bipyridine) as the photosensitizer and Na2 S2 O8 as… read more here.
Keywords: mechanism water; oxidation; water; water oxidation ... See more keywords
Insight into the Selective Methylene Oxidation Catalyzed by Mn(CF3-PDP)(SbF6)2/H2O2/CH2ClCO2H) System: A DFT Mechanistic Study.
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DOI: 10.1021/acs.orglett.0c04102
Abstract: DFT study was employed to gain insight into methylene oxidation catalyzed by Mn(CF3-PDP)(NCMe)2 (SbF6)2/H2O2/HOAcCl(OACCl ═OC(O)CH2Cl). The active catalyst was characterized to be [Mn](O)OAcCl ([Mn]═Mn(CF3-PDP)2+) which is generated via a sequence from [Mn] to [Mn]OH to… read more here.
Keywords: methylene oxidation; cf3 pdp; methylene; catalyzed cf3 ... See more keywords
Oriented External Electric Fields Regurating the Reaction Mechanism of CH4 Oxidation Catalyzed by Fe(IV)-Oxo-Corrolazine: Insight from Density Functional Calculations
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.896944
Abstract: Methane is the simplest alkane and can be used as an alternative energy source for oil and coal, but the greenhouse effect caused by its leakage into the air is not negligible, and its conversion… read more here.
Keywords: reaction; ch4 oxidation; energy; catalyzed oxo ... See more keywords