Chemo‐Enzymatic One‐Pot Oxidation of Cyclohexane via in‐situ H2O2 Production over Supported AuPdPt Catalysts
Sign Up to like & getrecommendations! Published in 2023 at "ChemCatChem"
DOI: 10.1002/cctc.202300162
Abstract: The introduction of dopant concentrations of Pt into supported AuPd nanoparticles, when used in conjunction with an evolved unspecific peroxygenase (UPO) from Agrocybe aegerita (PaDa‐I) is demonstrated to offer high efficacy towards the one‐pot selective… read more here.
Keywords: oxidation cyclohexane; h2o2 production; one pot; h2o2 ... See more keywords
Efficient and selective photocatalytic oxidation of cyclohexane using O2 as oxidant in VOCl2 solution and mechanism insight
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Engineering Science"
DOI: 10.1016/j.ces.2019.03.079
Abstract: Abstract The efficient selective oxidation of cyclohexane to cyclohexanone and cyclohexanol (KA-oil) under mild conditions remains one of the most challenging and interesting projects in catalytic chemistry. Here, photocatalytic oxidation of cyclohexane was carried out… read more here.
Keywords: photocatalytic oxidation; cyclohexane; oxidation; efficient selective ... See more keywords
Bio-gel template synthesis of CoFe2O4 nano-catalysts and application in aerobic oxidation of cyclohexane
Sign Up to like & getrecommendations! Published in 2017 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2017.05.072
Abstract: Abstract Magnetic cobalt ferrite (CoFe2O4) particles were synthesized via a solvothermal pathway by using the gel of natural lotus roots as bio-gel template. Samples with porous structure and of large specific area (∼95.6 m2/g) were prepared,… read more here.
Keywords: oxidation; aerobic oxidation; cofe2o4; oxidation cyclohexane ... See more keywords
Aerobic oxidation of cyclohexane catalyzed by graphene oxide: Effects of surface structure and functionalization
Sign Up to like & getrecommendations! Published in 2017 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2017.01.020
Abstract: Abstract Despite extensive development efforts on new catalysts for cyclohexane oxidation, current commercial processes are still desirable to further decrease the economic and environmental costs in the oxidation procedures. In this study, the catalyst properties… read more here.
Keywords: graphene oxide; oxidation; aerobic oxidation; structure ... See more keywords
Photothermal oxidation of cyclohexane by graphene oxide-based composites with high selectivity to KA oil
Sign Up to like & getrecommendations! Published in 2020 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2020.111103
Abstract: Abstract Designing high-performance catalyst for the oxidation of cyclohexane (CyH) into value-added products like cyclohexanol and cyclohexanone (the mixture called KA oil) is of paramount significance in chemical industry. Herein, the catalytic activity of graphene… read more here.
Keywords: graphene oxide; oxidation; oxidation cyclohexane; selectivity ... See more keywords
Selective Oxidation of Cyclohexane to Cyclohexanol/Cyclohexanone by Surface Peroxo Species on Cu-Mesoporous TiO2.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04196
Abstract: Selective oxidation of cyclohexane to cyclohexanol/cyclohexanone (KA-oil) is an important chemical process, which is still constrained by low conversion and selectivity and high energy consumption. In this study, Cu-doped mesoporous TiO2 (Cu-MT) has been successfully… read more here.
Keywords: cyclohexanol cyclohexanone; oxidation cyclohexane; selective oxidation; cyclohexane cyclohexanol ... See more keywords
The highly selective aerobic oxidation of cyclohexane to cyclohexanone and cyclohexanol over V2O5@TiO2 under simulated solar light irradiation
Sign Up to like & getrecommendations! Published in 2017 at "Green Chemistry"
DOI: 10.1039/c6gc02748b
Abstract: The highly selective aerobic oxidation of cyclohexane to cyclohexanone and cyclohexanol (KA-oil) under benign and green conditions is still a challenging topic. In this work, V2O5@TiO2 catalysts were prepared by V species deposited on TiO2… read more here.
Keywords: selective aerobic; v2o5 tio2; aerobic oxidation; oxidation cyclohexane ... See more keywords
Tuning of Activated Carbon for Solvent-Free Oxidation of Cyclohexane
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Chemistry"
DOI: 10.1155/2017/5732761
Abstract: Activated carbon (AC) was prepared from carbonization of phosphoric acid soaked peanut shell at 380°C under inert atmosphere followed by activation with hydrogen peroxide. The AC was characterized by SEM, EDX, FTIR, TGA, and BET… read more here.
Keywords: oxidation cyclohexane; free oxidation; solvent free; activated carbon ... See more keywords
The highly selective oxidation of cyclohexane to cyclohexanone and cyclohexanol over VAlPO4 berlinite by oxygen under atmospheric pressure
Sign Up to like & getrecommendations! Published in 2018 at "Chemistry Central Journal"
DOI: 10.1186/s13065-018-0405-6
Abstract: BackgroundThe oxidation of cyclohexane under mild conditions occupies an important position in the chemical industry. A few soluble transition metals were widely used as homogeneous catalysts in the industrial oxidation of cyclohexane. Because heterogeneous catalysts… read more here.
Keywords: oxygen; valpo4; selective oxidation; oxidation cyclohexane ... See more keywords
Efficient Oxidation of Cyclohexane over Bulk Nickel Oxide under Mild Conditions
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27103145
Abstract: Nickel oxide powder was prepared by simple calcination of nickel nitrate hexahydrate at 500 °C for 5 h and used as a catalyst for the oxidation of cyclohexane to produce the cyclohexanone and cyclohexanol—KA oil.… read more here.
Keywords: selectivity toward; cyclohexane; nickel oxide; oxidation cyclohexane ... See more keywords