Influence of Hydrophilicity on the Snβ‐Catalyzed Baeyer–Villiger Oxidation of Cyclohexanone with Aqueous Hydrogen Peroxide
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DOI: 10.1002/cctc.201600893
Abstract: Snβ zeolites are amongst the most effective heterogeneous catalysts for the Baeyer–Villiger (BV) oxidation of ketones with aqueous hydrogen peroxide (H2O2). The high selectivity is rooted in the activation of the carbonyl substrate through interaction… read more here.
Keywords: oxidation; baeyer villiger; hydrogen peroxide; aqueous hydrogen ... See more keywords
Oxidation of Cyclohexanone with Peracids—A Straight Path to the Synthesis of ε-Caprolactone Oligomers
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DOI: 10.3390/ma15196608
Abstract: During Baeyer–Villiger (BV) oxidation of cyclohexanone with peracids, oligo(ε-caprolactone) (OCL) may be formed. In this work, a two-step one-pot method for the synthesis of OCL involving the BV oxidation of cyclohexanone with peracids and then… read more here.
Keywords: oxidation cyclohexanone; cyclohexanone peracids; caprolactone; synthesis ... See more keywords