Selective Catalytic Oxidation of Cyclohexene with Molecular Oxygen: Radical Versus Nonradical Pathways
Sign Up to like & getrecommendations! Published in 2018 at "Chemcatchem"
DOI: 10.1002/cctc.201701538
Abstract: We study the allylic oxidation of cyclohexene with O2 under mild conditions in the presence of transition‐metal catalysts. The catalysts comprise nanometric metal oxide particles supported on porous N‐doped carbons (M/N:C, M=V, Cr, Fe, Co,… read more here.
Keywords: oxygen; oxidation; selective catalytic; free radical ... See more keywords
Selective allylic oxidation of cyclohexene over a novel nanostructured CeO2–Sm2O3/SiO2 catalyst
Sign Up to like & getrecommendations! Published in 2018 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-018-3482-1
Abstract: Selective allylic oxidation of cyclohexene was investigated over nanostructured CeO2/SiO2 and CeO2–Sm2O3/SiO2 catalysts synthesized by a feasible deposition precipitation method. The CeO2–Sm2O3/SiO2 catalyst showed excellent catalytic efficiency with ~89 % cyclohexene conversion and ~90 % selectivity for… read more here.
Keywords: sm2o3 sio2; sio2; cyclohexene; oxidation cyclohexene ... See more keywords
Increased selectivity for allylic oxidation of cyclohexene using TiO2 modified V2O5/MoO3 catalysts
Sign Up to like & getrecommendations! Published in 2017 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2017.05.023
Abstract: V2O5 and MoO3 mixed oxides supported by SiO2 were studied as the catalysts in the aqueous phase allylic oxidation of cyclohexene to unsaturated alcohol 2-cyclohexene-1-ol and unsaturated ketone 2-cyclohexene-1-one. The additional layer of TiO2 deposited… read more here.
Keywords: cyclohexene; v2o5 moo3; oxidation cyclohexene; allylic oxidation ... See more keywords
Modulation of the Activity of Gold Clusters Immobilized on Functionalized Mesoporous Materials in the Oxidation of Cyclohexene via the Functional Group. The Case of Aminopropyl Moiety
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25235756
Abstract: Gold nanoclusters and isolated gold atoms have been produced in a two-liquid phase procedure that involves a solution of gold in aqua regia and rosemary essential oil as organic layer. These gold entities have been… read more here.
Keywords: oxidation cyclohexene; activity; gold; functional group ... See more keywords