Electrochemically driven P–H oxidation and functionalization: synthesis of carbamoylphosphonates from phosphoramides and alcohols
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c8nj05739g
Abstract: Electrochemical synthesis of carbamoylphosphonates via P–H phosphorylation and oxygenation of phosphinecarboxamides with alcohols by using n-Bu4NI (10 mol%) as an iodine source. read more here.
Keywords: synthesis; oxidation functionalization; driven oxidation; synthesis carbamoylphosphonates ... See more keywords
Tracing and elucidating visible-light mediated oxidation and C-H functionalization of amines using mass spectrometry.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/c9cc09629a
Abstract: The co-existing mechanism of visible light mediated direct oxidation and C-H functionalization of amines was investigated by capturing all the intermediates using online mass spectrometry. The two-step dehydrogenation of amine involving a proton coupled electron… read more here.
Keywords: mass spectrometry; light mediated; visible light; functionalization amines ... See more keywords