Site-Selective Electrochemical Oxidation of Glycosides
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DOI: 10.1021/acscatal.2c06318
Abstract: Quinuclidine-mediated electrochemical oxidation of glycopyranosides provides C3-ketosaccharides with high selectivity and good yields. The method is a versatile alternative to Pd-catalyzed or photochemical oxidation and is complementary to the 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)-mediated C6-selective oxidation. Contrary… read more here.
Keywords: electrochemical oxidation; oxidation; site selective; oxidation glycosides ... See more keywords