Synthesis of Co(II) NNN-pyridine based complexes and their activity in the partial oxidation of n-octane
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.118992
Abstract: Abstract A series of four NNN-pyridine based ligands of the general form: pyCH2N(R)CH2py {R = propyl, tert-butyl, cyclohexyl and phenyl; py = pyridine} were synthesised and characterised. Complexation of each ligand to CoCl2·6H2O afforded new Co(II) complexes [Co{pyCH2N(R)CH2py}Cl2] (R = C3H7… read more here.
Keywords: synthesis nnn; pyridine based; oxidation octane; nnn pyridine ... See more keywords
Application of 1,2,3-triazolylidene nickel complexes for the catalytic oxidation of n-octane
Sign Up to like & getrecommendations! Published in 2017 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2017.03.005
Abstract: Half-sandwich nickel complexes bearing a variety of mesoionic N-heterocyclic carbene ligands (η5-cyclopentadienyl)-iodo-{1-(R)-3-methyl-4-phenyl-1H-1,2,3-triazol-3-ium-5-yl}nickel; where R = phenyl (3a); 2-ethoxy-2-oxoethyl (3b); propyl (3c); benzyl (3d) were synthesized by the reaction of nickelocene with the respective triazolium salts.… read more here.
Keywords: nickel; oxidation; nickel complexes; reaction ... See more keywords
The effects of metals and ligands on the oxidation of n-octane using iridium and rhodium “PNP” aminodiphosphine complexes
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Chemical Research"
DOI: 10.1177/1747519820967245
Abstract: Ir and Rh “PNP” complexes with different ligands are utilized for the oxidation of n-octane. Based on the obtained conversion, selectivity, and the characterized recovered catalysts, it is found that the combination of Ir and… read more here.
Keywords: ligands oxidation; pnp; metals ligands; effects metals ... See more keywords