Nickel(0) catalyzed oxidation of organosilanes to disiloxanes by air as an oxidant
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DOI: 10.1016/j.tetlet.2019.03.002
Abstract: Abstract We report here an efficient non-aqueous route to symmetrical disiloxanes from their corresponding organosilanes using Ni(COD)2 with 3,4,7,8-tetramethyl-1,10-phenanthroline in air. Our methodology is very simple and high yielding. The reaction mechanism is also proposed. read more here.
Keywords: oxidation organosilanes; nickel catalyzed; organosilanes disiloxanes; air ... See more keywords