Thiol dioxygenase turnover yields benzothiazole products from 2-mercaptoaniline and O2-dependent oxidation of primary alcohols.
Sign Up to like & getrecommendations! Published in 2017 at "Archives of biochemistry and biophysics"
DOI: 10.1016/j.abb.2017.08.013
Abstract: Thiol dioxygenases are non-heme mononuclear iron enzymes that catalyze the O2-dependent oxidation of free thiols (-SH) to produce the corresponding sulfinic acid (-SO2-). Previous chemical rescue studies identified a putative FeIII-O2- intermediate that precedes substrate… read more here.
Keywords: thiol dioxygenase; dependent oxidation; oxidation; primary alcohols ... See more keywords
Copper (II) immobilized on magnetically separable l-arginine-β-cyclodextrin ligand system as a robust and green catalyst for direct oxidation of primary alcohols and benzyl halides to acids in neat conditions
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121128
Abstract: Abstract Copper (II) immobilized on l -arginine-β-cyclodextrin-functionalized magnetite nanoparticles (nano-Fe3O4@ l -arginine-CD-Cu(II)) were successfully synthesized and fully characterized using FT-IR, XRD, SEM, EDX, ICP, TGA and VSM techniques. The catalytic activity of these magnetically retrievable… read more here.
Keywords: direct oxidation; arginine cyclodextrin; copper immobilized; primary alcohols ... See more keywords
Copper-catalyzed aerobic oxidation of primary alcohols to carboxylic acids.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00963g
Abstract: Here, the first copper-catalyzed aerobic oxidation of primary alcohols to carboxylic acids with TEMPO and KHSO4 as the co-catalysts has been developed. The reaction exhibits excellent substrate scope and functional group compatibility under mild conditions.… read more here.
Keywords: aerobic oxidation; oxidation primary; catalyzed aerobic; primary alcohols ... See more keywords
Single-Pot Synthesis of Alkyl-Substituted Quinolines and Indoles via Photoinduced Oxidation of Primary Alcohols
Sign Up to like & getrecommendations! Published in 2018 at "Russian Journal of General Chemistry"
DOI: 10.1134/s1070363218050080
Abstract: Single-pot synthesis of alkyl-substituted quinolines and indoles has been performed via photoinduced oxidation of primary aliphatic alcohols (C2–C5) and condensation of the aldehydes (products of the alcohols oxidation) with aniline under the action of iron-containing… read more here.
Keywords: oxidation; photoinduced oxidation; single pot; pot synthesis ... See more keywords