Metal-free visible-light-mediated aerobic oxidation of silanes to silanols
Sign Up to like & getrecommendations! Published in 2018 at "Science China Chemistry"
DOI: 10.1007/s11426-018-9289-9
Abstract: Oxidation of silanes into silanols using water/air has attracted considerable attention. The known methods with no exception required a metal catalyst. Herein we report the first metal-free method: 2 mol% Rose Bengal as the catalyst,… read more here.
Keywords: oxidation silanes; visible light; silanes silanols; free visible ... See more keywords
Copper-Containing Polyoxometalate-Based Metal-Organic Framework as a Catalyst for the Oxidation of Silanes: Effective Cooperative Catalysis by Metal Sites and POM Precursor.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03835
Abstract: The oxidation of silanes into silanols is a very necessary transformation, and yet the rational fabrication of efficient catalysts for this reaction remains a challenging task. Here, a 3D polyoxometalate-based metal-organic framework (POMOF), [CuΙ3(pz)3{PMo12O40}]·H2O (HENU-8,… read more here.
Keywords: oxidation; oxidation silanes; metal organic; polyoxometalate based ... See more keywords
Selective oxidation of silanes into silanols with water using [MnBr(CO)5] as a precatalyst
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc05959b
Abstract: The development of earth-abundant catalysts for the selective conversion of silanes to silanols with water as an oxidant generating valuable hydrogen as the only by-product continues to be a challenge. Here, we demonstrate that [MnBr(CO)5]… read more here.
Keywords: precatalyst; oxidation silanes; selective oxidation; silanes silanols ... See more keywords