Cationic Palladium(II) Complexes for Catalytic Wacker-Type Oxidation of Styrenes to Ketones using O2 as the Sole Oxidant
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700931
Abstract: A series of new palladium(II) complexes were prepared and studied for their ability to catalyze the Wacker-type oxidation of styrenes to their corresponding acetophenones using oxygen as the sole oxidant. Catalysts are active at room… read more here.
Keywords: sole oxidant; palladium complexes; wacker type; oxidation styrenes ... See more keywords
Redox Potential Controlled Selective Oxidation of Styrenes for Regio- and Stereoselective Crossed Intermolecular [2 + 2] Cycloaddition via Organophotoredox Catalysis.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01852
Abstract: A redox potential controlled intermolecular [2 + 2] cross-cycloaddition has been developed in the presence of a thioxanthylium photoredox catalyst. Electron-rich styrenes such as β-bromostyrene (Ep/2 = +1.61 V vs SCE) were selectively oxidized by… read more here.
Keywords: cycloaddition; redox potential; selective oxidation; oxidation styrenes ... See more keywords