Efficient and selective oxidation of tertiary benzylic C H bonds with O2 catalyzed by metalloporphyrins under mild and solvent-free conditions
Sign Up to like & getrecommendations! Published in 2020 at "Applied Catalysis A: General"
DOI: 10.1016/j.apcata.2020.117599
Abstract: Abstract The direct and efficient oxidation of tertiary benzylic C H bonds to alcohols with O2 was accomplished in the presence of metalloporphyrins as catalysts under solvent-free and additive-free conditions. Based on effective inhibition on… read more here.
Keywords: free conditions; oxidation; tertiary benzylic; oxidation tertiary ... See more keywords
Rose Bengal-photosensitized oxidation of tertiary amines for the synthesis of bis-1,3-dicarbonyl compounds
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DOI: 10.1016/j.tet.2017.09.050
Abstract: Abstract We report an example of Rose Bengal-photosensitized oxidation of tertiary amines for the synthesis of bis-1,3-dicarbonyl compounds. This protocol employs Rose Bengal as a visible-light absorbing photocatalyst without the need of a transition metal,… read more here.
Keywords: tertiary amines; amines synthesis; oxidation tertiary; bengal photosensitized ... See more keywords