Cobalt-Catalyzed Oxidative C-H Activation: Strategies and Concepts.
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DOI: 10.1002/cssc.202000024
Abstract: Inexpensive cobalt-catalyzed oxidative C-H functionalization has emerged as a powerful tool for the construction of C-C and C-Het bonds, which offers unique potential for transformative applications to modern organic synthesis. In the early stage, these… read more here.
Keywords: activation strategies; oxidative activation; catalyzed oxidative; cobalt catalyzed ... See more keywords
Catalytic Net Oxidative C-C Activation and Silylation of Cyclopropanols with a Traceless Acetal Directing Group.
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DOI: 10.1021/acscatal.1c04628
Abstract: Redox-neutral carbon-carbon (C-C) bond activation and functionalization strategies of cyclopropanols that give metallo homoenolate have offered merits to construct a range of useful β-functionalized ketones in an inverse-polarity fashion. Discovery and identification of oxidative C-C… read more here.
Keywords: net oxidative; silylation; oxidative activation; acetal directing ... See more keywords
Rapid wet-chemical oxidative activation of graphite felt electrodes for vanadium redox flow batteries
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DOI: 10.1039/d1ra05808h
Abstract: Schematic diagram of the K-GF fabrication process. Step 1: deposition of MnOx layers onto the P-GF electrode surface using acidified KMnO4 solutions. Step 2: removal of MnOx layers using an acidified H2O2 solution to produce… read more here.
Keywords: chemical oxidative; activation graphite; rapid wet; graphite felt ... See more keywords