The first principle computational study for the competitive mechanisms of oxidative aromatization of 2-substituted imidazolines using KMnO4/SiO2
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the Iranian Chemical Society"
DOI: 10.1007/s13738-017-1183-0
Abstract: AbstractThe efficiently oxidized various types of 2-substituted imidazolines to the corresponding imidazoles using potassium permanganate supported on silica gel (KMnO4/SiO2) under mild conditions and at room temperature have been reported before. In this study, the… read more here.
Keywords: using kmno4; mechanisms oxidative; study competitive; kmno4 sio2 ... See more keywords
Visible-Light-Induced Oxidation/[3 + 2] Cycloaddition/Oxidative Aromatization to Construct Benzo[a]carbazoles from 1,2,3,4-Tetrahydronaphthalene and Arylhydrazine Hydrochlorides.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b02939
Abstract: An efficient synthesis of benzo[a]carbazoles via visible-light-induced tandem oxidation/[3 + 2] cycloaddition/oxidative aromatization reactions was reported. The benzylic C(sp3)-H of tetrahydronaphthalene was activated through visible-light photoredox catalyst with oxygen as the clean oxidant under mild… read more here.
Keywords: light induced; visible light; oxidation cycloaddition; benzo carbazoles ... See more keywords
Heterogeneous mesoporous manganese oxide catalyst for aerobic and additive-free oxidative aromatization of N-heterocycles.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c6cc09095h
Abstract: Herein, we report a heterogeneous, aerobic, additive-free and environmentally benign catalytic protocol for oxidative aromatization of saturated nitrogen-heterocycles using a mesoporous manganese oxide material. The aromatized products can be separated by easy filtration and the… read more here.
Keywords: additive free; manganese oxide; mesoporous manganese; oxidative aromatization ... See more keywords
Enantioselective Synthesis of Atropisomers by Oxidative Aromatization with Central-to-Axial Conversion of Chirality
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28073142
Abstract: Atropisomers are fascinating objects of study by themselves for chemists but also find applications in various sub-fields of applied chemistry. Obtaining them in enantiopure form is far from being a solved challenge, and the past… read more here.
Keywords: oxidative aromatization; aromatization central; conversion chirality; central axial ... See more keywords