Palladium-catalyzed construction of amidines from arylsilanes in the absence of a ligand under oxidative conditions
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DOI: 10.1039/c8nj01883a
Abstract: An interesting palladium-catalyzed procedure for the synthesis of amidines from arylsilanes, isocyanides and amines has been developed. Moderate to good yields of the desired amidines were produced in the absence of a phosphine ligand under… read more here.
Keywords: construction amidines; oxidative conditions; amidines arylsilanes; catalyzed construction ... See more keywords
The regioselective coupling of 2-arylquinazolinone C–H with aldehydes and benzyl alcohols under oxidative conditions
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DOI: 10.1039/d0nj03721d
Abstract: The direct and regioselective palladium-catalyzed dehydrogenative coupling of aldehydes and benzyl alcohols with 2-aryl-quinazolinone C–H endowed with a quinazolinone nucleus, which is one of the most fascinating and vital core units, as an inherent directing… read more here.
Keywords: oxidative conditions; regioselective coupling; aldehydes benzyl; coupling arylquinazolinone ... See more keywords
Intrinsically High Capacity of Animal Cells From a Symbiotic Cnidarian to Deal With Pro-Oxidative Conditions
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DOI: 10.3389/fphys.2022.819111
Abstract: The cnidarian-dinoflagellate symbiosis is a mutualistic intracellular association based on the photosynthetic activity of the endosymbiont. This relationship involves significant constraints and requires co-evolution processes, such as an extensive capacity of the holobiont to counteract… read more here.
Keywords: cell; capacity; oxidative conditions; pro oxidative ... See more keywords