Transition Metal‐Free P‐Se Oxidative Cross‐Coupling for the Synthesis of Phosphoroselenothioates and Phosphoroselenoates
Sign Up to like & getrecommendations! Published in 2025 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.70223
Abstract: We report a one‐pot, transition metal‐free oxidative P‐Se cross‐coupling reaction for the synthesis of Se‐phosphoroselenothioates/phosphoroselenoates under ambient conditions. The reaction between phosphonothioates/phosphonates and diaryl diselenides proceeds efficiently within 3 h in acetonitrile under an oxygen… read more here.
Keywords: transition metal; cross coupling; metal free; oxidative cross ... See more keywords
Recent Progress in Decarboxylative Oxidative Cross‐Coupling for Biaryl Synthesis
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201700121
Abstract: The beginning of the 21st century has seen tremendous growth in the field of decarboxylative activation. Benzoic acid derivatives are now recognised as atom‐economic alternatives to traditional cross‐coupling partners, and they also benefit from being… read more here.
Keywords: decarboxylative oxidative; oxidative cross; cross; benzoic acid ... See more keywords
Laccase-catalyzed oxidative cross-linking of tyrosine and potato patatin- and lysozyme-derived peptides: Molecular and kinetic study.
Sign Up to like & getrecommendations! Published in 2021 at "Enzyme and microbial technology"
DOI: 10.1016/j.enzmictec.2020.109694
Abstract: Laccase can catalyze the oxidative cross-linking of peptides, which is useful in the production of proteinaceous materials with enhanced functional properties. However, the kinetics and the pathway of this reaction remain unclear. In the present… read more here.
Keywords: laccase catalyzed; study; oxidative cross; cross ... See more keywords
Tyrosinase Oxidative Cross-Linking in the Cell-Like Crowded Microenvironment for Visible Inhibitor Screening.
Sign Up to like & getrecommendations! Published in 2024 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.4c14010
Abstract: Owing to many diseases and disorders being caused by dysfunctional or over/underexpressed enzymes, screening for inhibitors of pharmacologically relevant enzymes has emerged as a promising tool for drug discovery, clinical diagnostics, enzyme engineering, and other… read more here.
Keywords: tyrosinase oxidative; oxidative cross; cross linking; cell like ... See more keywords
Regiodivergent Oxidative Cross-Coupling of Catechols with Persistent tert-Carbon Radicals
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DOI: 10.1021/acscatal.0c03986
Abstract: Oxidative cross-coupling is a powerful synthetic strategy for forming a carbon–carbon bond from two nucleophiles having C–H bonds. However, controlling the coupling selectivity (homo- vs cross-coup... read more here.
Keywords: regiodivergent oxidative; carbon; oxidative cross; cross ... See more keywords
Mechanistic Study on Cu(II)-Catalyzed Oxidative Cross-Coupling Reaction between Arenes and Boronic Acids under Aerobic Conditions.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b01896
Abstract: Substantial attention has been given to modern organocopper chemistry in recent years since copper salts are naturally abundant, cheap, and less toxic in comparison to precious metals. Copper salts also exhibit versatility in catalyzing and… read more here.
Keywords: chemistry; arcu iii; oxidative cross; reaction ... See more keywords
Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H2 evolution† †Electronic supplementary information (ESI) available. CCDC 1868011. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc05143g
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c8sc05143g
Abstract: Electrochemical oxidative C–H/S–H cross-coupling has been developed to construct the C–S bond in a highly straightforward and efficient manner. read more here.
Keywords: cross coupling; electrochemical oxidative; oxidative cross; coupling enamines ... See more keywords
Pd/C-catalyzed synthesis of oxamates by oxidative cross double carbonylation of alcohols and tertiary amines through C–N bond cleavage
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj04156g
Abstract: Palladium-catalyzed oxidative cross double carbonylation reaction between tertiary amines and alcohols using oxidant O2 and KI as the additive affords oxamates. Oxamate are as a intermediate in biological active compound and glycol synthesis. read more here.
Keywords: oxidative cross; cross double; double carbonylation; tertiary amines ... See more keywords
Palladium-catalyzed oxidative cross-coupling for the synthesis of α-amino ketones
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DOI: 10.1039/c9ra06108h
Abstract: A novel oxidative cross-coupling reaction for the synthesis of α-aryl α-amino ketones in the presence of palladium catalysts using T+BF4− as an oxidant has been developed. read more here.
Keywords: oxidative cross; synthesis; cross coupling; amino ketones ... See more keywords
Oxidative cross-coupling processes inspired by the Chan-Lam reaction.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc00213a
Abstract: The Cu-catalyzed oxidative cross-coupling of N- and O-nucleophiles with aryl boronic acids (the Chan-Lam reaction) remains among the most useful approaches to prepare aniline and phenol derivatives. The combination of high chemoselectivity, mild reaction conditions,… read more here.
Keywords: lam reaction; oxidative cross; reaction; cross coupling ... See more keywords
Palladium-catalyzed oxidative C-H/C-H cross-coupling of pyrazolo[1,5-a]azines with five-membered heteroarenes.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc06337e
Abstract: The use of Pd(OAc)2 as the catalyst and AgOAc as the oxidant enabled the direct regioselective oxidative C-H/C-H cross-coupling of pyrazolo[1,5-a]pyrimidines or pyrazolo[1,5-a]pyridines with various five-membered heteroarenes without the need of pre-activation and/or directing groups.… read more here.
Keywords: coupling pyrazolo; five membered; oxidative cross; cross coupling ... See more keywords