Curved Nanographene Featuring Two sp3 Stereocenters via Oxidative Cyclodehydrogenation with Aryl Rearrangement.
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DOI: 10.1021/acs.orglett.5c03555
Abstract: Curved nanographene 1, featuring two sp3 stereocenters, was synthesized through a Scholl-type oxidative cyclodehydrogenation accompanied by an unexpected aryl rearrangement. Single-crystal X-ray diffraction revealed that two sp3 carbons in the fused polycyclic skeleton induce pronounced… read more here.
Keywords: nanographene featuring; curved nanographene; featuring two; sp3 stereocenters ... See more keywords
CAN-Mediated Oxidative Cyclodehydrogenation of Hexapyrrolylbenzenes
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DOI: 10.1055/s-0040-1707822
Abstract: An efficient method for ceric ammonium nitrate mediated synthesis of annularly fused hexapyrrolohexaazacoronene by oxidative cyclodehydrogenation has been reported. The photophysical properties of the representative hexaazacoronene has also been described. read more here.
Keywords: oxidative cyclodehydrogenation; mediated oxidative; cyclodehydrogenation hexapyrrolylbenzenes; cyclodehydrogenation ... See more keywords