Oxidative insertion of amines into conjugated macrocycles: transformation of antiaromatic norcorrole into aromatic azacorrole.
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DOI: 10.1039/d2cc06648c
Abstract: A new group of aromatic porphyrinoids was obtained by an oxidative insertion of primary amines into the antiaromatic ring of 5,14-dimesityl-norcorrolatonickel(II) activated by iodosobenzene. The substituted 10-azacorroles thus formed were characterized by spectroscopic and electrochemical… read more here.
Keywords: conjugated macrocycles; macrocycles transformation; insertion amines; amines conjugated ... See more keywords