Oxidative kinetic resolution of P-chiral phosphines catalyzed by chiral (salen)dioxomolybdenum complexes
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DOI: 10.1016/j.mcat.2021.111776
Abstract: Abstract Synthetic LMoO2 compounds have long been of keen interest both as structural and functional models for molybdoenzymes and in their own right as catalysts for a variety of oxygen atom-transfer (OAT) reactions. Investigations of… read more here.
Keywords: chiral salen; oxidative kinetic; resolution chiral; kinetic resolution ... See more keywords
Oxidative Kinetic Resolution of cis-Fused Tricyclic 1-Tetralone Derivatives by Guanidine–Bisurea Bifunctional Organocatalyst
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DOI: 10.1055/s-0036-1588151
Abstract: We present an enantioselective synthesis of cis-fused tricyclic 1-tetralones via oxidative kinetic resolution in the presence of cumene hydroperoxide (CHP) and guanidine–bisurea bifunctional organocatalyst. This reaction affords the corresponding α-hydroxylation products together with unreacted tetralones… read more here.
Keywords: bisurea bifunctional; fused tricyclic; guanidine bisurea; kinetic resolution ... See more keywords