Biosynthesis of Annullatin D in Penicillium roqueforti Implies Oxidative Lactonization between Two Hydroxyl Groups Catalyzed by a BBE-like Enzyme.
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DOI: 10.1021/acs.orglett.2c02438
Abstract: Annullatins from Cordyceps annullata are alkylated aromatic polyketides including annullatin D with a fused dihydrobenzofuran lactone ring system. Here, we report the identification of a silent biosynthetic gene cluster for annullatins from Penicillium roqueforti by… read more here.
Keywords: oxidative lactonization; annullatin; hydroxyl groups; lactonization two ... See more keywords