Mn(OAc) 3 catalyzed intermolecular oxidative peroxycyclization of naphthoquinone
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DOI: 10.1039/c6ra25138b
Abstract: Manganese(III) acetate-mediated peroxycyclization between 2-hydroxy-3-methylnaphthoquinone and various alkenes was performed to obtain dihydronaphtho[2,3-c][1,2]dioxine-5,10(3H,10aH)-diones. The reactivity of symmetrical or unsymmetrical 1,1-disubstituted alkenes and monosubstituted alkenes allowed the synthesis of more than 50 original molecules. Focusing on… read more here.
Keywords: peroxycyclization; catalyzed intermolecular; peroxycyclization naphthoquinone; oxidative peroxycyclization ... See more keywords