PtOxCly(OH)z(H2O)n Complexes under Oxidative and Reductive Conditions: Impact of the Level of Theory on Thermodynamic Stabilities
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DOI: 10.1002/cphc.202200711
Abstract: Abstract Platinum‐based catalysts with Cl−, OH−, O2− and H2O ligands, are involved in many industrial processes. Their final chemical properties are impacted by calcination and reduction applied during the preparation and activation steps. We investigate… read more here.
Keywords: theory; h2o complexes; complexes oxidative; oxidative reductive ... See more keywords
Sequential Oxidative and Reductive Radical Cyclization Approach toward Asperparaline C and Synthesis of Its 8-Oxo Analogue.
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DOI: 10.1021/acs.orglett.7b00187
Abstract: The most advanced approach, so far, to the asperparalines is developed. Consecutive oxidative and reductive radical cyclizations serve as the key steps to stereoselectively access the complex fully elaborated skeleton containing the cyclopentane and spiro-succinimide… read more here.
Keywords: sequential oxidative; cyclization approach; radical cyclization; reductive radical ... See more keywords
Visible-Light Photoredox Catalyzed Oxidative/Reductive Cyclization Reaction of N-Cyanamide Alkenes for the Synthesis of Sulfonated Quinazolinones.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b02163
Abstract: An efficient photocatalytic oxidative/reductive cyclization reaction of N-cyanamide alkenes with arylsulfinic acids or arylsulfonyl chlorides, which proceeds through C-S, C-C, and C-N bond formations, is reported. This photocatalytic reaction was carried out under mild conditions,… read more here.
Keywords: sulfonated quinazolinones; reaction cyanamide; reductive cyclization; cyclization reaction ... See more keywords
A novel strategy to promote photo-oxidative and reductive abilities via the construction of a bipolar Bi2WO6/N-SrTiO3 material
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DOI: 10.1039/c7ra10932f
Abstract: Focusing on holistically promoting both photo-oxidative and reductive abilities, we constructed a novel Bi2WO6/N-SrTiO3 composite, which was expected to have excellent properties for the removal of complicated contaminants from solution environments under visible light irradiation.… read more here.
Keywords: bi2wo6 srtio3; photo oxidative; photo; oxidative reductive ... See more keywords