Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation.
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DOI: 10.1039/c9dt04230j
Abstract: The direct synthesis of neutral, divalent samarium and europium complexes supported by the bulky bis(tris-tert-butoxysilyl)amide (BTTSA) ligand via oxidative transmetallation is reported. Through the use of a copper(i) ligand complex, conventional lanthanide halide starting materials… read more here.
Keywords: via oxidative; divalent lanthanide; divalent; oxidative transmetallation ... See more keywords