Molybdenum Trihydride Complexes: Computational Model of Oxidatively Induced Reductive Elimination of Dihydrogen.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02805
Abstract: Recent experimental work shows that the 18-electron molybdenum complexes (1,2,4-C5H2tBu3)Mo(PMe3)2H3 (CptBuMoH3) and (C5HiPr4)Mo(PMe3)2H3 (CpiPrMoH3) undergo oxidatively induced reductive elimination of dihydrogen (H2), slowly forming the 15-electron monohydride species in tetrahydrofuran and acetonitrile. The 17-electron [CptBuMoH3]+… read more here.
Keywords: induced reductive; oxidatively induced; cptbumoh3; cpiprmoh3 ... See more keywords
Oxidatively induced reactivity in Rh(iii)-catalyzed 7-azaindole synthesis: insights into the role of the silver additive
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc01650h
Abstract: A typical synthetic protocol for preparing 7-azaindoles involves the coupling of 2-aminopyridine and alkyne substrates using a Rh(iii)-catalyst. The catalysis requires the assistance of an external Ag+ oxidant that is thought to regenerate the catalyst… read more here.
Keywords: oxidatively induced; role; azaindole synthesis; induced reactivity ... See more keywords