Reactivity of Atomic Oxygen Radical Anions in Metal Oxide Clusters.
Sign Up to like & getrecommendations! Published in 2024 at "ChemPlusChem"
DOI: 10.1002/cplu.202400085
Abstract: Atomic oxygen radical anion (O•-) represents an important type of reactive centre that exists in both chemical and biological systems. Gas-phase atomic clusters can be studied under isolated and well controlled conditions. Studies of O•--containing… read more here.
Keywords: chemistry; oxide clusters; metal oxide; atomic oxygen ... See more keywords
Entrapped Molecule-Like Europium-Oxide Clusters in Zinc Oxide with Nearly Unaffected Host Structure.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202203331
Abstract: Nanocrystalline ZnO sponges doped with 5 mol% EuO1.5 are obtained by heating metal-salt complex based precursor pastes at 200-900 °C for 3 min. X-ray diffraction, transmission electron microscopy, and extended X-ray absorption fine structure (EXAFS) show that… read more here.
Keywords: structure; oxide clusters; molecule like; zno ... See more keywords
Structure, fragmentation patterns, and electronic properties of small indium oxide clusters
Sign Up to like & getrecommendations! Published in 2018 at "Theoretical Chemistry Accounts"
DOI: 10.1007/s00214-018-2231-2
Abstract: A theoretical study of nanoparticles of indium oxide, one of the most relevant transparent conducting materials, is reported. By means of Density Functional Theory in the generalized gradient approximation, we investigated the atomic and electronic… read more here.
Keywords: structure fragmentation; patterns electronic; indium oxide; fragmentation patterns ... See more keywords
Cooperative desorption of H2O and CO from photo-excited cobalt oxide clusters: The evidence of photo-catalytic coupling
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2019.01.050
Abstract: Abstract The cooperative desorption of H2O and CO with 100% selectivity from the co-adsorbed cobalt oxide clusters CoxOyH2OCO+ [(x,y) = (3,3), (5,7), (6,9), and (9,12)] upon photo excitation at 355 nm was identified by mass spectrometry. In contrast,… read more here.
Keywords: desorption; catalytic coupling; cobalt oxide; photo catalytic ... See more keywords
A VUV photoionization time-of-flight mass spectrometer for the formation, distribution, and reaction of nano-sized neutral metal oxide clusters
Sign Up to like & getrecommendations! Published in 2017 at "International Journal of Mass Spectrometry"
DOI: 10.1016/j.ijms.2017.09.003
Abstract: Abstract It is experimentally challenging to generate and detect nano-sized neutral metal oxide clusters with high-resolution mass spectrometry. Herein, a vacuum ultraviolet (VUV) photoionization time-of-flight (TOF) mass spectrometer based instrument has been home-made to study… read more here.
Keywords: nano sized; neutral metal; mass; metal oxide ... See more keywords
Visible-light overall water splitting on g-C3N4 decorated by subnanometer oxide clusters
Sign Up to like & getrecommendations! Published in 2021 at "Materials Today Physics"
DOI: 10.1016/j.mtphys.2020.100312
Abstract: Abstract Two-dimensional (2D) nitrogenated holey carbon materials are promising non-precious photocatalysts for clean energy production. However, their efficiency is limited by the fast electron-hole recombination and lack of active sites. To overcome these drawbacks, here… read more here.
Keywords: water splitting; overall water; visible light; c3n4 ... See more keywords
C–H Bond Activation on Bimetallic Two-Atom Co-M Oxide Clusters Deposited on Zr-Based MOF Nodes: Effects of Doping at the Molecular Level
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b00012
Abstract: Cluster-based density functional theory calculations show that energy barriers for the dissociative adsorption of propane on two-cation, Co-M oxide clusters supported on Zr-based nodes of NU-1000, a metal–organic framework material, vary from 57 to 9… read more here.
Keywords: activation bimetallic; two atom; bond activation; bimetallic two ... See more keywords
The Hydroxyl Migration Mechanism through Vibrational Rocking Unveiled from Magic-Numbered Hydrated Lanthanum Oxide Clusters.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c09002
Abstract: A deep understanding of the structural evolution of metal oxide clusters and the migration of surface functional groups is of fundamental importance for understanding their catalytic mechanisms. However, due to the structural complexity and the… read more here.
Keywords: oxide clusters; migration; hydrated lanthanum; lanthanum oxide ... See more keywords
Nucleation mechanisms and speciation of metal oxide clusters†
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc03530k
Abstract: The self-assembly mechanisms of polyoxometalates (POMs) are still a matter of discussion owing to the difficult task of identifying all the chemical species and reactions involved. We present a new computational methodology that identifies the… read more here.
Keywords: mechanisms speciation; metal oxide; nucleation mechanisms; oxide clusters ... See more keywords
New picolinate-functionalized titanium-oxide clusters: syntheses, structures and photocatalytic H2 evolution.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01882a
Abstract: Two nanosized titanium-oxide clusters (TOCs), Ti12(μ2-O)14(μ3-O)4PA16 (1; PA = 2-picolinate) and Ti12(μ2-O)18PA18 (2) were synthesized by using 2-picolinic acid and Ti(OiPr)4 in one-pot reactions. Their structures were determined using single-crystal X-ray diffractometry. Although both have… read more here.
Keywords: new picolinate; oxide clusters; picolinate functionalized; titanium oxide ... See more keywords
Tuning the photodynamics of sub-nanometer neutral chromium oxide clusters through sequential oxidation.
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d2nr00464j
Abstract: Sub-nanometer neutral chromium oxide clusters were produced in the gas phase through laser ablation and their low-lying excited state lifetimes were measured using femtosecond pump-probe spectroscopy. Time-dependent density functional theory calculations relate the trends in… read more here.
Keywords: nanometer neutral; oxidation; chromium oxide; oxide clusters ... See more keywords