Syntheses, Crystal Structures, and Spectroscopic Studies of Uranyl Oxide Hydrate Phases with La(III)/Nd(III) Ions.
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DOI: 10.1021/acs.inorgchem.9b01102
Abstract: We have synthesized two uranyl oxide hydrate (UOH) phases incorporating La(III) or Nd(III) ions under hydrothermal conditions. Investigations with scanning electron microscopy and transmission electron microscopy (TEM) revealed thin-plate morphologies with a U-to-Ln atomic ratio… read more here.
Keywords: iii iii; iii ions; microscopy; oxide hydrate ... See more keywords
Uranyl oxide hydrate frameworks with lanthanide ions.
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DOI: 10.1039/d0dt02944k
Abstract: Two uranyl oxide hydrate frameworks (UOFs) incorporating either Eu(iii) or Gd(iii) ions were synthesized hydrothermally and structurally studied. The uranyl oxide hydroxide layers similar to those in β-U3O8 with both tetragonal and pentagonal bipyramidal uranium… read more here.
Keywords: hydrate frameworks; lanthanide ions; spectroscopy; oxide hydrate ... See more keywords
A family of uranyl oxide hydrate phases with bivalent cations [MII(H2O)4][(UO2)3O3(OH)2]·H2O (MII – Mn, Co, Ni, Zn): synthesis, characterization and chemical stability in aqueous solutions
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DOI: 10.1039/d1nj01414e
Abstract: A series of new uranium compounds [MII(H2O)3][(UO2)3O3(OH)2]·2H2O (MII – Mn, Co, Ni, Zn) were synthesized for binding radionuclides in the environment and nuclear fuel cycle. read more here.
Keywords: mii h2o; family uranyl; h2o uo2; uo2 3o3 ... See more keywords
Uranium oxide hydrate frameworks with Er(III) or Y(III) ions: revealing structural insights leading to the low symmetry.
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DOI: 10.1039/d2dt02763a
Abstract: Two new mixed-valence uranium oxide hydrate frameworks (UOFs), incorporating either Er3+ or Y3+ ions, were successfully synthesised under hydrothermal conditions and characterised with single-crystal X-ray diffraction and a variety of other structural and spectroscopic techniques.… read more here.
Keywords: uranium oxide; hydrate frameworks; oxide hydrate; frameworks iii ... See more keywords
Ni/cerium Molybdenum Oxide Hydrate Microflakes Composite Coatings Electrodeposited from Choline Chloride: Ethylene Glycol Deep Eutectic Solvent
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DOI: 10.3390/ma13040924
Abstract: Cerium molybdenum oxide hydrate microflakes are codeposited with nickel from a deep eutectic solvent-based bath. During seven days of exposure in 0.05 M NaCl solution, the corrosion resistance of composite coating (Ni/CeMoOxide) is slightly reduced,… read more here.
Keywords: chemistry; molybdenum oxide; cerium molybdenum; oxide hydrate ... See more keywords