Transition metal-free and regioselective vinylation of phosphine oxides and H-phosphinates with VBX reagents.
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DOI: 10.1039/d0cc05992g
Abstract: A series of phosphine oxides and H-phosphinates were vinylated in the presence of the iodine(iii) reagents vinylbenziodoxolones (VBX), providing the corresponding alk-1-enyl phosphine oxides and alk-1-enyl phosphinates in good yields with complete chemo- and regioselectivity.… read more here.
Keywords: vinylation; transition metal; phosphine; phosphine oxides ... See more keywords