Trapping an Oxidized and Protonated Intermediate of the [FeFe]-Hydrogenase Cofactor under Mildly Reducing Conditions.
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DOI: 10.1021/acs.inorgchem.2c00954
Abstract: The H-cluster is the catalytic cofactor of [FeFe]-hydrogenase, a metalloenzyme that catalyzes the formation of dihydrogen (H2). The catalytic diiron site of the H-cluster carries two cyanide and three carbon monoxide ligands, making it an… read more here.
Keywords: hydrogenase; oxidized protonated; cofactor; cluster ... See more keywords