Consensus structures of the Mo(v) sites of sulfite-oxidizing enzymes derived from variable frequency pulsed EPR spectroscopy, isotopic labelling and DFT calculations.
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DOI: 10.1039/c7dt01731f
Abstract: Sulfite-oxidizing enzymes from eukaryotes and prokaryotes have five-coordinate distorted square-pyramidal coordination about the molybdenum atom. The paramagnetic Mo(v) state is easily generated, and over the years four distinct CW EPR spectra have been identified, depending… read more here.
Keywords: frequency pulsed; spectroscopy isotopic; sulfite oxidizing; oxidizing enzymes ... See more keywords