Ultraviolet-Laser-Induced Electron Transfer from Peptides to an Oxidizing Matrix: Study of the First Step of MALDI In-Source Decay Mass Spectrometry.
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DOI: 10.1021/jasms.0c00186
Abstract: Although the N-H bond in peptide backbones is stronger than the C-H bond, hydrogen abstraction from the amide nitrogen is considered to be the initial step in the Cα-C bond cleavage of peptide backbones by… read more here.
Keywords: isd; bond; abstraction; oxidizing matrix ... See more keywords