Articles with "oxidovanadium complexes" as a keyword



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Synthesis and characterization of oxidovanadium complexes as enzyme inhibitors targeting dipeptidyl peptidase IV.

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Published in 2017 at "Journal of inorganic biochemistry"

DOI: 10.1016/j.jinorgbio.2017.06.014

Abstract: Two oxidovanadium(IV) complexes carrying Schiff base ligands obtained from the condensation of 4,5-dichlorobenzene-1,2-diamine and salicylaldehyde derivatives were synthesised and characterised, including their X-ray crystallographic structures. They were evaluated as dipeptidyl peptidase IV (DPP-IV) inhibitors for… read more here.

Keywords: characterization oxidovanadium; oxidovanadium; oxidovanadium complexes; dipeptidyl peptidase ... See more keywords
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Oxidovanadium (V and IV) complexes incorporating coumarin based O^N^O ligand: Synthesis, structure and catalytic activities

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Published in 2020 at "Polyhedron"

DOI: 10.1016/j.poly.2019.114241

Abstract: Abstract The tridentate ligand H2L1, [(E)-7-Hydroxy-8-[(2-hydroxy-phenylimino)-methyl]-4-methyl-chromen-2-one] has been used in the present work towards the synthesis of mononuclear oxidovanadium complexes. Three mononuclear complexes [VOL1(OMe)(MeOH)], 1; [VO(L1)(8-Hq)], 2 and [VO(L1)(1,10-phen)], 3 have been successfully synthesized with… read more here.

Keywords: coumarin based; oxidovanadium complexes; complexes incorporating; incorporating coumarin ... See more keywords
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Mono- and dinuclear oxidovanadium(v) complexes of an amine-bis(phenolate) ligand with bromo-peroxidase activities: synthesis, characterization, catalytic, kinetic and computational studies.

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Published in 2018 at "Dalton transactions"

DOI: 10.1039/c7dt04718e

Abstract: The mono- and dinuclear oxidovanadium(v) complexes [VVO(L1)(Cl)] (1) and [L1VVO(μ2-O)VO(L1)] (2) of ONNO donor amine-bis(phenolate) ligand (H2L1) were readily synthesized by the reaction between H2L1 and VCl3.(THF)3 or VO(acac)2 in MeOH or MeCN, respectively, and… read more here.

Keywords: mono dinuclear; amine bis; bis phenolate; oxidovanadium complexes ... See more keywords
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EPR and 51V NMR studies of prospective anti-diabetic bis(3-hydroxy-4-pyridinonato)oxidovanadium(IV) complexes in aqueous solution and liposome suspensions

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Published in 2018 at "New Journal of Chemistry"

DOI: 10.1039/c7nj04678b

Abstract: We report EPR and 51V NMR characterization of vanadium(IV/V) species originating from bis(3-hydroxy-4-pyridinonato)oxidovanadium(IV) complexes in aqueous solution at pH 7.4, under aerobic conditions and along time. Since complexes possess variable hydrophilic/lipophilic balance and consequently different… read more here.

Keywords: 51v nmr; hydroxy pyridinonato; oxidovanadium complexes; pyridinonato oxidovanadium ... See more keywords

Synthesis of oxidovanadium complexes containing coumarin and naphthalene: bromoperoxidase activity and DNA/BSA binding

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Published in 2023 at "Journal of Coordination Chemistry"

DOI: 10.1080/00958972.2023.2205002

Abstract: Abstract Two tridentate Schiff base ligands, L1 and L2 , have been introduced in the synthesis of mononuclear oxidovanadium complexes with a co-ligand 1,10-phenanthroline. Two mononuclear complexes, [VO(L1)(1,10-phen)] (1) and [VO(L2)(1,10-phen)] (2), have been synthesized… read more here.

Keywords: oxidovanadium complexes; dna bsa; synthesis;
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Two Oxidovanadium(V) Complexes with Hydrazone Ligands: Synthesis, Crystal Structures and Catalytic Oxidation Property.

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Published in 2022 at "Acta chimica Slovenica"

DOI: 10.17344/acsi.2021.7296

Abstract: Two new oxidovanadium(V) complexes, [VOL1(aha)]DMF (1) and [VOL2(mat)] (2), where L1 and L2 are the dianionic form of N'-(4-bromo-2-hydroxybenzylidene)-3-methyl-4-nitrobenzohydrazide and N'-(3,5-dibromo-2-hydroxybenzylidene)pivalohydrazide, respectively, and aha and mat are the monoanionic form of acetohydroxamic acid and maltol,… read more here.

Keywords: complexes hydrazone; oxidovanadium complexes; two oxidovanadium; crystal structures ... See more keywords
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Syntheses, Structures and Insulin-Like Activity of Two Oxidovanadium(V) Complexes with Similar Nicotinohydrazone Ligands.

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Published in 2022 at "Acta chimica Slovenica"

DOI: 10.17344/acsi.2022.7605

Abstract: Two new oxidovanadium(V) complexes, [VOL1(HQ)] (1) and [VOL2(SAH)] (2), were prepared by the reaction of [VO(acac)2] (where acac = acetylacetonate) with N'-(3-ethoxy-2-hydroxybenzylidene)nicotinohydrazide (H2L1) and 8-hydroxyquinoline (HHQ), and N'-(2-hydroxy-4-methoxybenzylidene)nicotinohydrazide (H2L2) and salicylhydroxamic acid (HSAH), respectively, in… read more here.

Keywords: insulin like; oxidovanadium complexes; oxidovanadium; syntheses structures ... See more keywords
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Study of DNA Interaction and Cytotoxicity Activity of Oxidovanadium(V) Complexes with ONO Donor Schiff Base Ligands

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Published in 2021 at "Inorganics"

DOI: 10.3390/inorganics9090066

Abstract: Two new oxidovanadium(V) complexes, (HNEt3)[VVO2L] (1) and [(VVOL)2μ-O] (2), have been synthesized using a tridentate Schiff base ligand H2L [where H2L = 4-((E)-(2-hydroxy-5-nitrophenylimino)methyl)benzene-1,3-diol] and VO(acac)2 as starting metal precursor. The ligand and corresponding metal complexes… read more here.

Keywords: interaction; oxidovanadium complexes; cytotoxicity; schiff base ... See more keywords
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QSAR Modeling, Molecular Docking and Cytotoxic Evaluation for Novel Oxidovanadium(IV) Complexes as Colon Anticancer Agents

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Published in 2022 at "Molecules"

DOI: 10.3390/molecules27030649

Abstract: Four new drug-based oxidovanadium (IV) complexes were synthesized and characterized by various spectral techniques, including molar conductance, magnetic measurements, and thermogravimetric analysis. Moreover, optimal structures geometry for all syntheses was obtained by the Gaussian09 program… read more here.

Keywords: oxidovanadium complexes; ctz 2h2o; molecular docking; qsar modeling ... See more keywords