Theoretical prediction of the synthesis of 2,3-dihydropyridines through Ir(III)-catalysed reaction of unsaturated oximes with alkenes
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DOI: 10.1039/c6ra25501a
Abstract: In spite of their widespread use as catalysts, 1,2,3,4,5-pentamethylcyclopentadienyl (Cp*) iridium complexes have been rarely employed in the synthesis of pyridine derivatives. Herein, we used density functional theory (DFT) calculations to predict the [Cp*Ir(OAc)]+-catalysed synthesis… read more here.
Keywords: unsaturated oxime; migratory insertion; synthesis dihydropyridines; reaction ... See more keywords