Decoding the reaction mechanism of the cyclocondensation of ethyl acetate2‐oxo‐2‐(4‐oxo‐4H‐pyrido [1.2‐a] pyrimidin‐3‐yl) polyazaheterocycle and ethylenediamine using bond evolution theory
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26853
Abstract: We investigated the flow of electron density along the cyclocondensation reaction between ethyl acetate 2‐oxo‐2‐(4‐oxo‐4H‐pyrido[1.2‐a]pyrimidin‐3‐yl) polyazaheterocycle (1) and ethylenediamine (2) at the ωB97XD/6–311++G(d,p)computational method within of bond evolution theory (BET). The exploration of potential energy… read more here.
Keywords: oxo; reaction; oxo pyrido; pyrido pyrimidin ... See more keywords
Is pre‐heat necessary for the measurement of 8‐oxo‐7,8‐dihydroguanosine and 8‐oxo‐7,8‐dihydro‐2′‐deoxyguanosine in urine samples
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Clinical Laboratory Analysis"
DOI: 10.1002/jcla.24674
Abstract: It is currently unclear for the necessary of pre‐heating urine samples for the accurate determination of 8‐oxo‐7,8‐dihydroguanosine (8‐oxoG) and 8‐oxo‐7,8‐dihydro‐2′‐deoxyguanosine (8‐oxodG). Thus, we conducted this study to evaluate the effect of pre‐heat (i.e., to 37°C)… read more here.
Keywords: oxo; oxo dihydro; oxo dihydroguanosine; pre heat ... See more keywords
Reply to commentary on “Is pre‐heat necessary for the measurement of 8‐oxo‐7,8‐dihydroguanosine and 8‐oxo‐7,8‐dihydro‐2′‐deoxyguanosine in urine samples”
Sign Up to like & getrecommendations! Published in 2023 at "Journal of Clinical Laboratory Analysis"
DOI: 10.1002/jcla.24873
Abstract: We thoroughly read the commentary from Hu et al. to our recently published article 1 and admire their work. To make our point clearer and better clarify the necessity of pre- heat for the accurate… read more here.
Keywords: oxo dihydroguanosine; oxo; oxo dihydro; pre heat ... See more keywords
Commentary on: Is preheat necessary for the measurement of 8‐oxo‐7,8‐dihydroguanosine and 8‐oxo‐7,8‐dihydro‐2′‐deoxyguanosine in urine samples
Sign Up to like & getrecommendations! Published in 2023 at "Journal of Clinical Laboratory Analysis"
DOI: 10.1002/jcla.24874
Abstract: 1Department of Public Health, Chung Shan Medical University, Taichung 402, Taiwan 2Oxidative Stress Group, Department of Cell Biology, Microbiology and Molecular Biology, University of South Florida, Tampa, Florida 33620, USA 3Department of Occupational Safety and… read more here.
Keywords: oxo; medical university; biology; taichung 402 ... See more keywords
Sodium 2-Oxo-3-(3-oxo-1-phenylbutyl)-2H-chromen-4-olate as Green Corrosion Inhibitor for Mild Steel in 1 M HCl Medium: A Combined Experimental and Theoretical Study
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Bio- and Tribo-Corrosion"
DOI: 10.1007/s40735-019-0226-8
Abstract: The effect of Sodium 2-oxo-3-(3-oxo-1-phenylbutyl)-2H-chromen-4-olate against the corrosion of mild steel in 1 M HCl solution was investigated using weight loss and electrochemical methods. The results show that inhibition efficiency increases with increased inhibitor concentration from… read more here.
Keywords: sodium oxo; inhibitor; oxo; oxo phenylbutyl ... See more keywords
Self-assembly of a new 3D platelike ternary-oxo-cluster: An efficient catalyst for the synthesis of pyrazoles
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2021.05.008
Abstract: Abstract A new metal-oxo-clusters-based inorganic framework [NaCo2Mo2O7(OH)3]n (NaCoMo), named as 3D platelike ternary-oxo-cluster, has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction structure analysis, FT-IR spectroscopy, powder X-ray diffraction (PXRD), scanning electron microscope (SEM),… read more here.
Keywords: new platelike; oxo cluster; ternary oxo; spectroscopy ... See more keywords
Visible light generation of high-valent metal-oxo intermediates and mechanistic insights into catalytic oxidations.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2020.111246
Abstract: High-valent metal-oxo complexes play central roles as active oxygen atom transfer (OAT) agents in many enzymatic and synthetic oxidation catalysis. This review focuses on our recent advances in application of photochemical approaches to probe the… read more here.
Keywords: oxo species; oxo; valent metal; high valent ... See more keywords
Organic-Inorganic High-Valence Sn18-oxo Clusters: Direct Utilization of an Inorganic Sn(IV) Source to Improve the Nuclearity and Electrocatalytic CO2 Reduction Properties.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00038
Abstract: The high-valence tin-oxo clusters are of great significance because of their structural diversity and potential applications in many fields, e.g., catalysis, extreme ultraviolet (EUV) lithography, and so on. The synthesis of high-nuclearity tin-oxo clusters remains… read more here.
Keywords: oxo clusters; sn18 oxo; tin; oxo ... See more keywords
Space-Confined Nucleation of Semimetal-Oxo Clusters within a [H7P8W48O184]33- Macrocycle: Synthesis, Structure, and Enhanced Proton Conductivity.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03543
Abstract: Spatially confined assembly of semimetallic oxyanions (AsO33- and SbO33-) within a [H7P8W48O184]33- (P8W48) macrocycle has afforded three nanoscale polyanions, [{AsIII5O4(OH)3}2(P8W48O184)]32- (As10), [(SbIIIOH)4(P8W48O184)]32- (Sb4), and [(SbIIIOH)8(P8W48O184)]24- (Sb8), which were crystallized as the hydrated mixed-cation salts (Me2NH2)13K7Na2Li10[{AsIII5O4(OH)3}2(P8W48O184)]·32H2O… read more here.
Keywords: sbiiioh p8w48o184; oxo; semimetal oxo; chemistry ... See more keywords
Structural and Spectroscopic Investigation of Novel 2D and 3D Uranium Oxo-Silicates/Germanates and Some Statistical Aspects of Uranyl Coordination in Oxo-Salts.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01523
Abstract: Synthesis, structural and spectroscopic characterization, and topological analysis of five novel uranyl-based silicates and germanates have been performed. The open-framework K4(UO2)2Si8O20·4H2O has been synthesized under hydrothermal conditions and is based upon [USi6] heptamers interconnected via… read more here.
Keywords: coordination; oxo; investigation; structural spectroscopic ... See more keywords
Computational Study on the Light-Induced Oxidation of Iridium-Aqua Complex to Iridium-Oxo Complex over WO3(001) Surface.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02704
Abstract: An iridium aqua complex [IrIII(η5-C5Me5){bpy(COOH)2}(H2O)]2+ under visible light irradiation has been experimentally reported to form an iridium-oxo (Ir-oxo) complex [IrV(η5-C5Me5){bpy(COOH)2}(O)]2+, which oxidizes H2O to O2. However, the mechanism for the formation of this Ir-oxo complex… read more here.
Keywords: oxo; light induced; iridium; oxo complex ... See more keywords